Decomposition of methane hydrate for hydrogen production using microwave and radio frequency in-liquid plasma methods

Ismail, Rahim and Shinfuku, Nomura and Shinobu, Mukasa and Hiromichi, Toyota (2015) Decomposition of methane hydrate for hydrogen production using microwave and radio frequency in-liquid plasma methods. Applied Thermal Engineering, 90 (11). ISSN 1359-4311

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Abstract

This research involves two in-liquid plasma methods of methane hydrate decomposition, one using radio frequency wave (RF) irradiation and the other microwave radiation (MW). The ultimate goal of this research is to develop a practical process for decomposition of methane hydrate directly at the subsea site for fuel gas production. The mechanism for methane hydrate decomposition begins with the dissociation process of methane hydrate formed by CH4 and water. The process continues with the simultaneously occurring steam methane reforming process and methane cracking reaction, during which the methane hydrate is decomposed releasing CH4 into H2, CO and other by-products. It was found that methane hydrate can be decomposed with a faster rate of CH4 release using microwave irradiation over that using radio frequency irradiation. However, the radio frequency plasma method produces hydrogen with a purity of 63.1% and a CH conversion ratio of 99.1%, which is higher than using microwave plasma method which produces hydrogen with a purity of 42.1% and CH4 conversion ratio of 85.5%.

Item Type: Article
Uncontrolled Keywords: Methane hydrate In-liquid plasma Radio frequency Microwave oven Decomposition Hydrogen production
Subjects: FAKULTAS TEKNIK
FAKULTAS TEKNIK > Pendidikan Teknik Otomotif
KARYA ILMIAH DOSEN
Universitas Negeri Makassar > KARYA ILMIAH DOSEN
Divisions: KOLEKSI KARYA ILMIAH UPT PERPUSTAKAAN UNM MENURUT FAKULTAS > KARYA ILMIAH DOSEN
KARYA ILMIAH DOSEN
Depositing User: Dr.Eng. Ismail Rahim
Date Deposited: 01 Feb 2022 07:11
Last Modified: 01 Feb 2022 07:11
URI: http://eprints.unm.ac.id/id/eprint/21548

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